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How, Fiona Ni Foong and Watkins, David J. and Crouse, Karen Anne and Tahir, Mohamed Ibrahim Mohamed (2007) S-Quinolin-2-ylmethyldithiocarbazate. Acta Crystallographica Section E Structure Reports Online, E63. o3137-o3138. ISSN 1600-5368 E-ISSN 2056-9890

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In the title compound, C11H11N2S2, there is an intramolecular N—H...N [2.778(2) Angstrom] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7(1)deg with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)deg] and N—C—S [119.05 (11)deg] are comparable with cis–trans S-methyldithiocarbazate but differ from those found in trans–cis S-methyldithiocarbazate and trans–cis S-benzyldithiocarbazate. This is due to the N—H..N hydrogen bond that exists only in the cis–trans conformation found for the title compound.

Item Type: Article (Journal)
Additional Information: 6467/44882
Uncontrolled Keywords: : single-crystal X-ray study; T = 150 K; mean �(C–C) = 0.002 A˚; R factor = 0.038; wR factor = 0.079; data-to-parameter ratio = 18.7.
Subjects: Q Science > QD Chemistry
Kulliyyahs/Centres/Divisions/Institutes (Can select more than one option. Press CONTROL button): Kulliyyah of Science
Depositing User: Dr Fiona How
Date Deposited: 24 Feb 2016 11:37
Last Modified: 18 Jul 2016 14:28
URI: http://irep.iium.edu.my/id/eprint/44882

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