Determination of polar aromatic amines using newly synthesized sol–gel titanium (IV) butoxide cyanopropyltriethoxysilane

Miskam, Mazidatulakmam and Mohamad, Sharifah and Abu Bakar, Nor Kartini (2014) Determination of polar aromatic amines using newly synthesized sol–gel titanium (IV) butoxide cyanopropyltriethoxysilane. Talanta , 120. pp. 450-455. ISSN 0039-9140

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Abstract

A solid phase extraction (SPE) method has been developed using a newly synthesized titanium (IV) butoxide-cyanopropyltriethoxysilane (Ti-CNPrTEOS) sorbent for polar selective extraction of aromatic amines in river water sample. The effect of different parameters on the extraction recovery was studied using the SPE method. The applicability of the sorbents for the extraction of polar aromatic amines by the SPE was extensively studied and evaluated as a function of pH, conditioning solvent, sample loading volume, elution solvent and elution solvent volume. The optimum experimental conditions were sample at pH 7, dichloromethane as conditioning solvent, 10 mL sample loading volume and 5 mL of acetonitrile as the eluting solvent. Under the optimum conditions, the limit of detection (LOD) and limit of quantification (LOQ) for solid phase extraction using Ti-CNPrTEOS SPE sorbent (0.01-0.2; 0.03-0.61 µg L(-1)) were lower compared with those achieved using Si-CN SPE sorbent (0.25-1.50; 1.96-3.59 µg L(-1)) and C18 SPE sorbent (0.37-0.98; 1.87-2.87 µg L(-1)) with higher selectivity towards the extraction of polar aromatic amines. The optimized procedure was successfully applied for the solid phase extraction method of selected aromatic amines in river water, waste water and tap water samples prior to the gas chromatography-flame ionization detector separation.

Item Type:	Article (Journal)
Additional Information:	7122/43216
Uncontrolled Keywords:	Solid phase extraction Titanium(IV) butoxidecyanopropyltriethoxysilane sorbent Aromatic amines Gas chromatograpy–flame ionization detector
Subjects:	Q Science > QD Chemistry
Kulliyyahs/Centres/Divisions/Institutes (Can select more than one option. Press CONTROL button):	Kulliyyah of Science > Department of Chemistry
Depositing User:	Dr MAZIDATULAKMAM MISKAM
Date Deposited:	09 Jun 2015 09:32
Last Modified:	06 Jul 2015 12:09
URI:	http://irep.iium.edu.my/id/eprint/43216

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