Monte Carlo simulations of gas‐phase collisions in rapid desorption of molecules from surfaces

Ibrahim Ali , Noorbatcha and Lucchese, Robert R. and Zeiri, Yehuda (1987) Monte Carlo simulations of gas‐phase collisions in rapid desorption of molecules from surfaces. Journal of Chemical Physics , 86 (10). 5816 -5824. ISSN 0021-9606

PDF - Published Version Restricted to Repository staff only Download (920kB) | Request a copy

Abstract

We have examined the effects of collisions among the molecules desorbing from solid surfaces by means of Monte Carlo simulations, and have identified the conditions under which and to what extent these collisions would influence the experimentally observed product distributions. By simulating the experiment performed by Cowin e t a l. [Surf. Sci. 7 8, 545 (1978)] on the laser induced desorption of D2 from tungsten, we have found that at high coverages each desorbate makes on average 2.9 collisions which decreases to no collisions at very low coverages. These collisions affect the product distribution at high coverages to such an extent that even if the nascent desorbed flux is under thermal equilibrium, these post‐desorption collisions could lead to nonequilibrium distributions. The effect of the post‐desorption collisions is influenced by the rate of heating the surface and the kinetics of the desorption process.

Item Type:	Article (Journal)
Additional Information:	3704/37067
Uncontrolled Keywords:	Monte Carlo simulation
Subjects:	Q Science > QD Chemistry
Kulliyyahs/Centres/Divisions/Institutes (Can select more than one option. Press CONTROL button):	Kulliyyah of Engineering > Department of Biotechnology Engineering
Depositing User:	Prof. Dr. Ibrahim Ali Noorbatcha
Date Deposited:	27 Jun 2014 10:01
Last Modified:	27 Jun 2014 10:01
URI:	http://irep.iium.edu.my/id/eprint/37067

Actions (login required)

View Item