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Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran

Card, Roger J. and Omar, Muhammad Nor (1977) Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran. Sains Malaysiana, 6 (2). pp. 133-138. ISSN 0126-6039

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Abstract

The photolysis of 1-octene and molybdenum hexacarbonyl in tetrahydrofuran results in isomerization of the olefin. When the concentration of molybdenum hexacarbonyl is greater than 0.05M less than 1 mole of the isomerized olefin is producedfor each mole of molybdenum hexacarbonyl. The efficiency of the isomerization decreases as the concentration of molybdenum hexacarbonyl is increased. Under the condition used, the isomerization was initially rapid, but stopped completely after approximately 10 minutes.

Item Type: Article (Journal)
Additional Information: 5626/30235
Subjects: Q Science > QD Chemistry
Kulliyyahs/Centres/Divisions/Institutes: Kulliyyah of Science > Department of Biotechnology
Depositing User: Prof Dr Muhammad Nor Omar
Date Deposited: 05 Aug 2013 11:07
Last Modified: 25 Jun 2016 15:47
URI: http://irep.iium.edu.my/id/eprint/30235

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