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Thermal, mechanical and rheological properties of poly (lactic acid)/epoxidized soybean oil blends

Ali, Fathilah and Chang, Young-Wook and Kang, Shin Choon and Yoon, Joon Yong (2009) Thermal, mechanical and rheological properties of poly (lactic acid)/epoxidized soybean oil blends. Polymer Bulletin, 62 (1). pp. 91-98. ISSN 0170-0839

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Abstract

Poly(lactic acid) (PLA) was melt blended with epoxidized soybean oil (ESO) in an internal mixer and thermal, mechanical and rheological properties of the blends were investigated by means of differential scanning calorimetry, dynamic mechanical analysis, tensile test and small amplitude oscillatory shear rheometry. ESO lowered glass transition temperature and increased the ability of PLA to cold crystallization. The blend exhibited improved elongation-at-break along with a plastic deformation. The plasticization effect by ESO was also manifested by the lowering of dynamic storage modulus and viscosity in the melt state of the blends compared with neat PLA.

Item Type: Article (Journal)
Additional Information: 5439/11835
Uncontrolled Keywords: poly(lactic acid), epoxidized soybean,
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Kulliyyahs/Centres/Divisions/Institutes (Can select more than one option. Press CONTROL button): Kulliyyah of Engineering > Department of Biotechnology Engineering
Depositing User: Nur' Aini Abu Bakar
Date Deposited: 25 Dec 2011 09:58
Last Modified: 25 Dec 2011 10:08
URI: http://irep.iium.edu.my/id/eprint/11385

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